To add Facebook testers:
- Go to https://developers.facebook.com/
- Go to My Apps > Choose the app of the Facebook Page
- From the left panel, go to Roles > Roles
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- To add Administrators, click on Add Administrator
- To add Developers, click on Add Developers
- To add Testers, click on Add Testers
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- Add the Facebook User ID of the person you want to add
The username or Facebook ID can be found on the user's profile here:
https://www.facebook.com/FACEBOOK_USER_ID